| 1. Killing Is My Business...And Business Is Good! (Remix) | not rated | 3:02 |
| 2. Keeping Score | not rated | 1:35 |
| 3. Trust | not rated | 5:11 |
| 4. Intro/Rattlehead (Live At Wembley) | not rated | 5:55 |
| 5. The Skull Beneath the Skin (Remix) | not rated | 3:45 |
| 6. Symphony of Destruction | not rated | 4:06 |
| 7. Almost Honest | not rated | 4:08 |
| 8. Wake Up Dead (Live At Wembley) | not rated | 3:53 |
| 9. Go to Hell | not rated | 4:35 |
| 10. Peace Sells | not rated | 4:02 |
| 11. Use the Man | not rated | 4:03 |
| 12. Hangar 18 (Live At Wembley) | not rated | 4:52 |
| 13. Foreclosure of a Dream | not rated | 4:22 |
| 14. She-Wolf | not rated | 3:37 |
| 15. Wake Up Dead | not rated | 3:37 |
| 16. Hook In Mouth (Live At Wembley) | not rated | 4:27 |
| 17. Devil's Island | not rated | 5:05 |
| 18. Architecture of Aggression (Demo) | not rated | 2:49 |
| 19. A Secret Place (Live At Woodstock '99) | not rated | 4:31 |
| 20. The Skull Beneath the Skin (Live At Wembley) | not rated | 3:30 |
| 21. Skin O' My Teeth (Live from Alpine Valley) | not rated | 3:18 |
| 22. Set the World Afire | not rated | 5:48 |
| 23. One Thing | not rated | 4:38 |
| 24. The Conjuring (Live At Wembley) | not rated | 4:48 |
| 25. Into the Lungs of Hell | not rated | 3:22 |
| 26. Duke Nukem | not rated | 3:54 |
| 27. High Speed Dirt (Live At Alpine Valley) | not rated | 4:07 |
| 28. In My Darkest Hour (Live At Wembley) | not rated | 5:42 |
| 29. Ashes In Your Mouth (Live Cow Palace) | not rated | 6:15 |
| 30. Insomnia | not rated | 4:16 |
| 31. Anarchy/Problems (Session Take) | not rated | 3:51 |
| 32. Lucretia (Live At Wembley) | not rated | 3:42 |
| 33. Sweating Bullets (Live from Cow Palace / San Francisco) | not rated | 4:52 |
| 34. Crush 'Em | not rated | 4:54 |
| 35. Hook In Mouth | not rated | 4:40 |
| 36. Devil's Island (Live At Wembley) | not rated | 4:45 |
| 37. Liar | not rated | 3:20 |
| 38. Kill the King | not rated | 3:44 |
| 39. Breakpoint (Session Take) | not rated | 3:17 |
| 40. Take No Prisoners (Live At Wembley) | not rated | 3:17 |
| 41. Dread & the Fugitive Mind | not rated | 4:22 |
| 42. In My Darkest Hour | not rated | 6:26 |
| 43. Angry Again | not rated | 3:47 |
| 44. Peace Sells (Live At Wembley) | not rated | 4:12 |
| 45. Train of Consequences | not rated | 3:31 |
| 46. Never Say Die (Edited) | not rated | 3:46 |
| 47. No More Mr. Nice Guy | not rated | 3:00 |
| 48. Black Friday (Live At Wembley) | not rated | 6:10 |
| 49. Moto Psycho | not rated | 3:06 |
| 50. Dark Themes (Interview Excerpt) | not rated | 0:36 |
| 51. Reckoning Day | not rated | 4:34 |
| 52. Megadeth with Sean Harris - It's Electric (Live At Wembley) | not rated | 3:22 |
| 53. New World Order (Demo) | not rated | 3:47 |
| 54. 1000 Times Goodbye | not rated | 6:25 |
| 55. Holy Wars...The Punishment Due (Casey McMackin Demo) | not rated | 6:42 |
| 56. Anarchy In the UK (Live At Wembley) | not rated | 3:04 |
| 57. Tornado of Souls (Demo) | not rated | 5:18 |
| 58. The Killing Road | not rated | 3:51 |
| 59. Coming Home | not rated | 2:39 |
| 60. Holy Wars...The Punishment Due (Live At Wembley) | not rated | 6:42 |
| 61. Five Magics (Demo) | not rated | 5:37 |
| 62. Kick the Chair | not rated | 3:57 |
| 63. Strange Ways | not rated | 2:45 |
| 64. Paranoid | not rated | 2:31 |
| 65. Hangar 18 | not rated | 5:11 |
| 66. Of Mice and Men | not rated | 4:05 |
| 67. Diadems | not rated | 4:17 |
| 68. A Tout Le Monde | not rated | 4:22 |
| 4:46:09 |
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